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Dynamics of Ultrafast Intramolecular Charge Transfer with 4-(Dimethylamino)benzonitrile in Acetonitrile †

✍ Scribed by Druzhinin, Sergey I.; Ernsting, Nikolaus P.; Kovalenko, Sergey A.; Lustres, Luis Pérez; Senyushkina, Tamara A.; Zachariasse, Klaas A.


Book ID
120973283
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
741 KB
Volume
110
Category
Article
ISSN
1089-5639

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The femtosecond dynamics of 4-(N,N-dimethylamino)-4'-cyanostilbene (DCS) in acetonitrile and methanol solvent was studied by fluorescence upconversion and pump-probe absorption spectroscopy. The spectral evolution observed provides strong evidence for a fast internal charge-transfer (CT) process dom