Excited state intramolecular charge transfer reaction in 4-(1-azetidinyl)benzonitrile: Solvent isotope effects
โ Scribed by Tuhin Pradhan; Piue Ghoshal; Ranjit Biswas
- Book ID
- 107584466
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 2009
- Tongue
- English
- Weight
- 374 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0253-4134
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๐ SIMILAR VOLUMES
## Abstract The timeโdependent density functional theory (TDDFT) method was carried out to investigate the hydrogenโbonded intramolecular chargeโtransfer (ICT) excited state of 4โdimethylaminobenzonitrile (DMABN) in methanol (MeOH) solvent. We demonstrated that the intermolecular hydrogen bond CโกNยท
The rate of formation of the intramolecular charge-transfer state of 4-(N,N-dimethylamino)benzonitrile (DMABN) has been determined in supercritical CFsH using a fast single-photon counting technique. The rate constant increases rapidly with increasing CFIH density, indicating the importance of the p