Solvent dependences of spectral and redox properties of pyrazine (pz) complexes of ruthenium and osmium pentaammines: Ru(NH3)5pzCH33+, OS(NH3)5pzCH33+, and [Ru(NH3)5]2pz5+
✍ Scribed by Creutz, Carol; Chou, Mei H.
- Book ID
- 115511209
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 804 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i
## Abstract The kinetics of replacement of H~2~O by [Ru(NH~3~)pz]^2+^ (pz = pyrazine) in [Fe(CN)~5~H~2~O]^3−^ have been studied in various concentrated electrolyte solutions and in various water–cosolvent mixtures, at 298 K. Salt and cosolvent effects can be rationalized taking into account specifi
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