## Abstract The kinetics of replacement of H~2~O by [Ru(NH~3~)pz]^2+^ (pz = pyrazine) in [Fe(CN)~5~H~2~O]^3−^ have been studied in various concentrated electrolyte solutions and in various water–cosolvent mixtures, at 298 K. Salt and cosolvent effects can be rationalized taking into account specifi
Kinetic Approach for the Study of Noncovalent Interaction between [Ru(NH 3 ) 5 pz] 2+ and Gold Nanoparticles
✍ Scribed by Grueso, E.; Alcantara, D.; Martinez, J.; Mancera, M.; Penades, S.; Sanchez, F.; Pradogotor, R.
- Book ID
- 126954041
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 158 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i
## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__