## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i
✦ LIBER ✦
Estimation of Electron Transfer Rate Constant from Static (Optical and Thermodynamic) Measurements: A Study of Ru(NH 3 ) 5 pz 2+ + Fe(CN) 63- ⇌ Ru(NH 3 ) 5 pz 3+ + Fe(CN) 64- Electron Transfer Reactions
✍ Scribed by Sánchez, F.; Pérez-Tejeda, P.; López-López, M.
- Book ID
- 127050919
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 54 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__