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Solvent-Controlled Selectivity in the Synthesis of Five-Membered Carbocycles from Carbene Complexes

โœ Scribed by Florencio Zaragoza Doerwald


Publisher
John Wiley and Sons
Year
2003
Weight
56 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract Fischer carbene complexes react with 4โ€unsubstituted 1โ€aminoโ€1,3โ€dienes to give different carbocyclization products depending on the nature of the carbene complex and on the substitution pattern of the aminodiene. Thus, the reaction of arylcarbene chromium complexes and 1โ€aminodienes di