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Solvent-Controlled Selectivity in the Synthesis of Five-Membered Carbocycles from Carbene Complexes

✍ Scribed by Florencio Zaragoza Dörwald


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
87 KB
Volume
42
Category
Article
ISSN
0044-8249

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## Abstract Fischer carbene complexes react with 4‐unsubstituted 1‐amino‐1,3‐dienes to give different carbocyclization products depending on the nature of the carbene complex and on the substitution pattern of the aminodiene. Thus, the reaction of arylcarbene chromium complexes and 1‐aminodienes di