## Abstract Fischer carbene complexes react with 4‐unsubstituted 1‐amino‐1,3‐dienes to give different carbocyclization products depending on the nature of the carbene complex and on the substitution pattern of the aminodiene. Thus, the reaction of arylcarbene chromium complexes and 1‐aminodienes di
✦ LIBER ✦
ChemInform Abstract: Diastereoselective Synthesis of Three-, Five-, Six-, and Seven-Membered Rings from Fischer Carbene Complexes and 4-Unsubstituted 1-Amino-1,3-dienes.
✍ Scribed by Fernando Aznar; Martin Fananas-Mastral; Jorge Alonso; Francisco J. Fananas
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 42 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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## Abstract β‐Substituted alkenylcarbene complexes react with methyl ketone lithium enolates to give different carbocyclization products depending on the structure of the lithium enolate, on the metal of the carbene complex, and on the reaction media. Thus, the reactions of aryl and alkyl methyl ke