The temporal behavior of the 07 -center quartet-state emission in calcium oxide has been studied as a function of temperature. The enhanced phosphorescence decay rate at higher temperatures is attributed to an Orbach-type thermalization among the quartet-state spin sublevels.
✦ LIBER ✦
Solvent and temperature dependence of the phosphorescence decay time of hexacyanochromate (III)
✍ Scribed by R. Dannöhl-Fickler; H. Kelm; F. Wasgestian
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 695 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0022-2313
No coin nor oath required. For personal study only.
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## Phosphorescence decay has been measured at liquid helium tcmpcrntures for 2,2'dipyridyl, l,lO-phennntllroline and their tris and bis compleses with rhodium(lI1). The decay for the free lignnds and bis complcscs is exponential with lifetimes shorter than those measured at 77°K. The decay for th