Solvent and Structural Effects on the Photoreduction of Cobalt(III)-Aryl Amine Complexes in Water–Organic Solvent Media*
✍ Scribed by G. Karthikeyan; K. Anbalagan; K. P. Elango
- Book ID
- 110433922
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2003
- Tongue
- English
- Weight
- 61 KB
- Volume
- 29
- Category
- Article
- ISSN
- 1070-3284
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The kinetics of base hydrolysis of some (aminomonocarboxylato)(tetraethylenepentamine)cobalt(III) complexes, [(tetren have been investigated in methanol-water media (0-80 vol % MeOH) at 15.0 Յ tЊC Յ 40.0 (0.02 mol dm Ϫ3 NaOH). The second-order rate constant at zero ionic strength, k 2 Њ, increases
## Abstract The aquation of K‐[Co(dien)(en)Cl]^2+^ was followed spectrophotometrically within the temperature range (40–60°C) in water, water–isopropyl alcohol, and water–__tert__‐butyl alcohol media of varying solvent composition up to 50 and 60 vol% of the organic solvent component respectively.
The kinetics of base hydrolysis of (CUPS) (salicylato) (tetraethylenepentamine) cobalt(II1) have been investigated in aquo-organic solvent media at 15.0 f t, "C < 40.0, and I = 0.10 mol dm (C104-) using propane-2-01 (570% v/v), t-butanol(560% v/v), acetone (570% v/v, acetonitrile (550% v/v), and eth