Solvent H-bonding and structural effects on the photo-reduction of Co(III) complexes in water/propan-2-ol and water/1,4-dioxane media

Effect of solvent on the reactions of co

Effect of solvent on the reactions of coordination complexes. Part 10. kinetics of solvolysis of cis(chloro)(1-amino-propan-2-ol)bis-(ethylenediamine)cobalt(III) in methanol + water, propan-2-ol + water, and t-butanol + water media

✍ Anadi C. Dash; Prafulla K. Das 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 574 KB

## Abstract The solvolysis of __cis__(chloro)(1‐amino‐propan‐2‐ol)bis(ethylenediamine)cobalt(III) in aqueous alcoholic media using methanol, propan‐2‐ol, __t__‐butanol as cosolvents, resulted in the formation of the (N,O) chelated product__cis__[Co(en)~2~(NH~2~CH~2~CHOHCH~3~)]^3+^. The pseudo first