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Effects of solvent on the reactions of coordination complexes. part 24. kinetics of base hydrolysis of some (aminomonocarboxylato)(tetraethylene-pentamine)cobalt(III) complexes in methanol+water media: The role of substrate hydrophobicity and solvent structure

✍ Scribed by Anadi C. Dash; Achyuta N. Acharya; Smrutiprava Das

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 199 KB
Volume: 31
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1999)31:1<55::aid-kin7>3.0.co;2-n

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✦ Synopsis

The kinetics of base hydrolysis of some (aminomonocarboxylato)(tetraethylenepentamine)cobalt(III) complexes, [(tetren

have been investigated in methanol-water media (0-80 vol % MeOH) at 15.0 Յ tЊC Յ 40.0 (0.02 mol dm Ϫ3 NaOH). The second-order rate constant at zero ionic strength, k 2 Њ, increases