Reactivity trends are reported for aquation of tris(5-nitro-1,10-phenanthroline)iron(II) in ternary H20-t-BuOHpolyethyleneglycol (PEG400) solvent media. Wavelengths of maximum absorption for the lowest energy chargetransfer band of dicyanobis(2-acetylpyridineoximato)iron(II) are reported for the sam
Solvatochromism and solvation of ternary iron-diimine-cyanide complexes
✍ Scribed by John Burgess; Stojan Radulović; Francisco Sánchez
- Publisher
- Springer
- Year
- 1987
- Tongue
- English
- Weight
- 750 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0340-4285
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📜 SIMILAR VOLUMES
Solvent, pressure, and temperature effects on charge-transfer spectra of several iron( and iron-(III)-diimine-cyanide complexes are described. The effects for MLCT and LMCT bands are in opposite direction; the solvatochromic, piezochromic, and thermochromic behaviour of the iron(I1) complexes paral
Kinetic results are presented for dissociation (aquation) of low-spin tris-diimine-iron(II) complexes derived from 2-pyridinealdoxime, 2-acetylpyridineketoxime and 2benzoylpyridineketoxime in acidic aqueous and mixed aqueous media. The preparation and solvatochromic behaviour are described for terna