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Piezochromic and thermochromic behaviour of ternary diimine–cyanide–Iron(II) and –Iron(III) complexes

✍ Scribed by M. Kotowski; R. Van Eldik; Razak Bin Ali; J. Burgess; S. Radulović

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
373 KB
Volume
131
Category
Article
ISSN
0020-1693

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✦ Synopsis

Solvent, pressure, and temperature effects on charge-transfer spectra of several iron( and iron-(III)-diimine-cyanide complexes are described. The effects for MLCT and LMCT bands are in opposite direction;

the solvatochromic, piezochromic, and thermochromic behaviour of the iron(I1) complexes parallels that of molybdenum(O)-carbonyl-diimine complexes.

📜 SIMILAR VOLUMES

Complexes of iron(III) and iron(II) with
Complexes of iron(III) and iron(II) with o-nitrosophenols (mono-oximes of ortho-benzoquinones)
✍ J Charalambous; M.J Frazer; R Sims 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 475 KB

## Complexes of the type Fe(qo), have been prepared, where qoH = I nitroso-2-naphthol, 2-nitroso-I -naphthol, phenanthrene-9, IO-quinonemono-oxime, 5-methoxy-2-nitrosophenol, 5-methyl-2-nitrosophenol and 4,5-dimethyl-2-nitrosophenol. Some of the complexes react with hydrochloric acid to give FeCl(qo