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Kinetic and solvatochromic behaviour of low-spin iron(II) complexes of pyridineoximate and dioximate ligands

✍ Scribed by E. -E. A. Abu-Gharib; J. Burgess

Publisher
Springer
Year
1993
Tongue
English
Weight
437 KB
Volume
18
Category
Article
ISSN
0340-4285

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✦ Synopsis

Kinetic results are presented for dissociation (aquation) of low-spin tris-diimine-iron(II) complexes derived from 2-pyridinealdoxime, 2-acetylpyridineketoxime and 2benzoylpyridineketoxime in acidic aqueous and mixed aqueous media. The preparation and solvatochromic behaviour are described for ternary bis-diimine-dicyanoiron(II) complexes derived from 2-acetylpyridineketoxime and from four dioximes. These results are considered in relation to hydration and (selective) solvation of these ligands and their complexes.

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