Specific beat me~u~ments for Fe(phy)\*~~O~)~ and Fe(pby)\*(BF~)~ are reported in the spin transition region. A maximum in C, is observed at & due to the &t-order character of the spin-state transition. The value of C,, for high-spin states is greater than that for low-spin states. The derived values
✦ LIBER ✦
A Mössbauer study of structure and bonding in iron(II) and iron(III) low-spin compounds with 1,10-phenanthroline and 2,2′-bipyridyl ligands
✍ Scribed by V.K. Garg; N. Malathi; S.P. Puri
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 464 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0009-2614
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## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole