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Solid state vibrational spectroscopy of disordered crystals. A study of dimethylsulphoxide at 213 K

✍ Scribed by S. Bianco; R.S. Cataliotti; S. Chieli; F. Guerrini; C. Gaburri; G. Paliani; A. Peraio; M. Scamosci; C. Schioppa; C. Taratza

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
357 KB
Volume
42
Category
Article
ISSN
1386-1425

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✦ Synopsis

vibrational spectrum of crystalline diiethylsulphoxide at 213 K has been studied by i.r. and Raman spectroscopy. Such an experiment is proposed as an example to show how much the dipole-dipole interaction forces can a!Te-ct the molecular disorder often observed in molecular crystals of compounds containing sulphur atoms.

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Solid state vibrational spectroscopy. 10
Solid state vibrational spectroscopy. 10β€”A kinetic study, using Raman spectroscopy, of the solid state thermal decompositions of sodium and potassium dithionate
✍ Kevin D. Cleaver; J. Eric D. Davies πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 155 KB

The kinetic behaviour of the solid state thermal decomposition of dithionate to sulphate, M2[Sz0,] + M,[SO,], M = Na, K, has been studied by following the temporal decrease in the intensity of the Raman band arising from the v,(SO,) mode of [S2O6]". The sodium salt displays first order kinetics, but