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Solid state vibrational spectroscopy. 8—A thermochemical and vibrational spectroscopic study of the solid state thermal decompositions of alkali metal peroxydisulphates

✍ Scribed by Kevin D. Cleaver; J. Eric D. Davies


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
348 KB
Volume
9
Category
Article
ISSN
0377-0486

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Solid state vibrational spectroscopy. 10
✍ Kevin D. Cleaver; J. Eric D. Davies 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB

The kinetic behaviour of the solid state thermal decomposition of dithionate to sulphate, M2[Sz0,] + M,[SO,], M = Na, K, has been studied by following the temporal decrease in the intensity of the Raman band arising from the v,(SO,) mode of [S2O6]". The sodium salt displays first order kinetics, but