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Solid-State Synthesis and Structural Characterization of Hydrated Zinc (II) Tartrate Complex

✍ Scribed by Bei-Gang Li; Jing Mi; Feng-Mei Nie

Publisher
Springer
Year
2009
Tongue
English
Weight
385 KB
Volume
40
Category
Article
ISSN
1572-8854

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Both 1 : 1 and 1 : 2 complexes are formed by zinc(II) halides and triarylphosphines unless electronic and/or steric factors intervene. Tri-p-chlorophosphine (a weaker base than PPh 3 ) forms only a 1 : 1 complex, whereas bulky tri-(ortho-substituted phenyl)phosphines do not react. The complexes ZnX