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Synthesis and structural characterization of zinc(II) acetate complex with α-isosparteine

✍ Scribed by Beata Jasiewicz; Władysław Boczoń; Teresa Borowiak; Irena Wolska


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
438 KB
Volume
875
Category
Article
ISSN
0022-2860

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Both 1 : 1 and 1 : 2 complexes are formed by zinc(II) halides and triarylphosphines unless electronic and/or steric factors intervene. Tri-p-chlorophosphine (a weaker base than PPh 3 ) forms only a 1 : 1 complex, whereas bulky tri-(ortho-substituted phenyl)phosphines do not react. The complexes ZnX