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Synthesis, spectral and structural characterization of three zinc(II) azide complexes with aminopyrazine

✍ Scribed by Mohamed A.S. Goher; Franz A. Mautner; Beate Sodin; Brigitte Bitschnau


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
837 KB
Volume
879
Category
Article
ISSN
0022-2860

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✍ Mohamed A.S. Goher; Brigitte Bitschnau; Beate Sodin; Christian Gspan; Franz A. M πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 850 KB

Three new polymeric zinc(II) azido complexes, namely [Zn(N 3 ) 2 (3-Brpy)] n (1), [Zn(N 3 ) 2 (4-Etpy)] n (2) and [Zn 2 (N 3 ) 4 (2,5-dmpyz)] n (3), where Brpy = bromopyridine, Etpy = ethylpyridine and dmpyz = dimethylpyrazine have been prepared and structurally characterized. The IR spectra of thes

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The reaction of the lithium Ξ²-diketoiminate complex (dipp with ZnCl 2 yielded the corresponding (dipp)NacNacZnCl ( 1) and (dipp)NacNacZn(Β΅-Cl) 2 Li(OEt 2 ) 2 (1a). Treatment of 1 with LiCΟ΅CPh and NaBH 4 in diethyl ether gave (dipp)Nac-NacZnCΟ΅CPh ( 2) and (dipp)NacNacZn(Β΅-H) 2 BH 2 (3). The core ele

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Both 1 : 1 and 1 : 2 complexes are formed by zinc(II) halides and triarylphosphines unless electronic and/or steric factors intervene. Tri-p-chlorophosphine (a weaker base than PPh 3 ) forms only a 1 : 1 complex, whereas bulky tri-(ortho-substituted phenyl)phosphines do not react. The complexes ZnX