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Solid state studies. XII—the vibrational spectra of mixed crystals of (C6H5)3PMxM′1-x(CO)5 where M, M′ = Cr, Mo, W

✍ Scribed by David N. Kariuki; Sidney F. A. Kettle


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
586 KB
Volume
6
Category
Article
ISSN
0377-0486

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✦ Synopsis


Abstract

The high molecular symmetry (C~4ν~) and single crystal structure (P~1,~, Z = 2) of the title compounds permit an analysis of their vibrational spectra in the 2000 cm^−1^ region in terms of modal behaviour. This analysis is confirmed by spectral measurements on mixed crystals.


📜 SIMILAR VOLUMES


Solid state studies. Pt. XVI. The μ(CO)
✍ S.L. Barker; L. Harland; S.F. Kettle; F.F. Stephens 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 328 KB

Pure and mixed crystal studies and intensity calculations have been carried out on the v(C0) features of $-CSH5Fe(CO),M(C~5)3, M = Sn, Ge. This work demonstrates the presence of intermolecular vibrational coupling and supports the proposal that the vibrational unit cell of the tin compound is one ha