Pure and mixed crystal studies and intensity calculations have been carried out on the v(C0) features of $-CSH5Fe(CO),M(C~5)3, M = Sn, Ge. This work demonstrates the presence of intermolecular vibrational coupling and supports the proposal that the vibrational unit cell of the tin compound is one ha
✦ LIBER ✦
Solid state studies. XII—the vibrational spectra of mixed crystals of (C6H5)3PMxM′1-x(CO)5 where M, M′ = Cr, Mo, W
✍ Scribed by David N. Kariuki; Sidney F. A. Kettle
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 586 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0377-0486
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✦ Synopsis
Abstract
The high molecular symmetry (C~4ν~) and single crystal structure (P~1,~, Z = 2) of the title compounds permit an analysis of their vibrational spectra in the 2000 cm^−1^ region in terms of modal behaviour. This analysis is confirmed by spectral measurements on mixed crystals.
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