The v(C0) infrared and Raman spectra of a series of related qs-C5HsFe(CO)zX (X = Sn or Ge species) compounds are reported. Relative band intensities give evidence of intensity stealing by an intermolecular vibrational coupling mechanism.
✦ LIBER ✦
Solid state studies. Pt. XVI. The μ(CO) vibrational spectra of η5-C5H5Fe(CO)2M(C6H2)3, M = Sn, Ge
✍ Scribed by S.L. Barker; L. Harland; S.F. Kettle; F.F. Stephens
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 328 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0020-1693
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✦ Synopsis
Pure and mixed crystal studies and intensity calculations have been carried out on the v(C0) features of $-CSH5Fe(CO),M(C~5)3, M = Sn, Ge. This work demonstrates the presence of intermolecular vibrational coupling and supports the proposal that the vibrational unit cell of the tin compound is one half of the crystallographic.
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