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Solid state coordination chemistry of the copper cyanide–organoamine system: hydrothermal synthesis and structural characterization of [{Cu2(bpy)2(CN)}2Cu5(CN)7]·0.17H2O

✍ Scribed by Chesnut, Douglas J.; Kusnetzow, Anakarin; Zubieta, Jon


Book ID
118742307
Publisher
The Royal Society of Chemistry
Year
1998
Tongue
English
Weight
340 KB
Volume
24
Category
Article
ISSN
1472-7773

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Investigations of the Copper Bromide–Eth
✍ Robert P. Hammond; Douglas J. Chesnut; Jon A. Zubieta 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 429 KB

The hydrothermal reactions of CuBr 2 , CuBr, and ethylenediamine have resulted in the synthesis of two new compounds. [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 2 Br 4 }] has a two-dimensional sheet structure while [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 5 Br 7 }] crystallizes as a three-dimensional network. Bot