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Solid state coordination chemistry of the copper(II)/bisterpy/vanadate system: The structures of [Cu2(bisterpy)V4O12]·2H2O and [Cu2(bisterpy)V4F2O11] (bisterpy = 2,2′:4′,4′′:2′′,2′′′-quarter-pyridyl, 6′,6′′-di-2-pyridine)

✍ Scribed by Wayne Ouellette; Jon Zubieta


Book ID
113913273
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
565 KB
Volume
9
Category
Article
ISSN
1293-2558

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A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU