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Hydrothermal synthesis and structures of the open-framework copper silicates Na2[Cu2Si4O11](H2O)2 (CuSH-2Na), Na2[CuSi3O8] (CuSH-3Na), Cs2Na4[Cu2Si12O27(OH)2](OH)2 (CuSH-4NaCs), and Na2[Cu2Si5O13](H2O)3 (CuSH-6Na)

✍ Scribed by Xiqu Wang; Lumei Liu; Lingbao Wang; Allan J. Jacobson

Book ID
113913023
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
896 KB
Volume
7
Category
Article
ISSN
1293-2558

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## Abstract Pure‐phase copper silicate, Na~2~Cu~2~Si~4~O~11~Β·2H~2~O (AV‐23), was synthesized hydrothermally by starting with a molar ratio of CuO:3.2SiO~2~:3.02Na~2~O:4.57NH~3~:146H~2~O. To avoid the formation of polycrystalline CuO, aqueous ammonia was used as complexing agent. The inductively cou