Soft-X-ray-Induced Redox Isomerism in a Cobalt Dioxolene Complex
✍ Scribed by Giordano Poneti; Matteo Mannini; Lorenzo Sorace; Philippe Sainctavit; Marie-Anne Arrio; Edwige Otero; Julio Criginski Cezar; Andrea Dei
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 404 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
An electronic switch at the molecular level has been realized by using a class of ionic compounds of the formula [Co(L)(diox)]Y (L tetraazamacrocyclic ligand, Y mononegative anion). Such compounds undergo temperature-and pressure-induced intramolecular one-electron transfer equilibria. The transitio
O-bonded amide complexes of platinum(II), which are stable species due to the higher affinity of platinum for nitrogen donors. In contrast O-bonded amides owe their stability to in acetone solution and which undergo solvolysis in neat water with a rate constant as slow as 8.7•10 -5 s -1 , are their