Pressure- and Temperature-Induced Valenc
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Andrea Caneschi; Andrea Dei; Fabrizia Fabrizi de Biani; Philipp Gütlich; Vadim K
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Article
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2001
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John Wiley and Sons
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English
⚖ 113 KB
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An electronic switch at the molecular level has been realized by using a class of ionic compounds of the formula [Co(L)(diox)]Y (L tetraazamacrocyclic ligand, Y mononegative anion). Such compounds undergo temperature-and pressure-induced intramolecular one-electron transfer equilibria. The transitio