Sodium trifluoromethanesulfonate acetonitrile solvate
✍ Scribed by Meffre, A. ;Barboiu, M. ;Lee, A. van der
- Book ID
- 104489216
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 266 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the twofold-symmetric dinuclear title compound, [Ag 2 (C 14 H 11 N 3 S) 2 (CH 3 CN) 2 ](CF 3 SO 3 ) 2 , each Ag I atom is coordinated by one N atom and one S atom from one 8-(pyrimidin-2-ylsulfanylmethyl)quinoline ligand, one N atom from a second 8-(pyrimidin-2-ylsulfanylmethyl)quinoline ligand,
The title mononuclear complex, [Ag(C 15 H 12 N 2 S) 2 ]CF 3 SO 3 , reveals the molecular symmetry C 2 with the Ag atom located on a crystallographic twofold axis. The Ag I centre is coordinated by two pyridine N-donors of two 8-(4pyridylsulfanylmethyl)quinoline ligands in an almost linear geometry.