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Bis[μ-8-(pyrimidin-2-ylsulfanylmeth­yl)quinoline-κ2N,S]bis­[(acetonitrile)silver(I)] bis­(trifluoro­methane­sulfonate)

✍ Scribed by Song, Rui-Feng ;Wang, Yu-Hong ;Li, Jian-Rong

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
145 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the twofold-symmetric dinuclear title compound, [Ag 2 (C 14 H 11 N 3 S) 2 (CH 3 CN) 2 ](CF 3 SO 3 ) 2 , each Ag I atom is coordinated by one N atom and one S atom from one 8-(pyrimidin-2-ylsulfanylmethyl)quinoline ligand, one N atom from a second 8-(pyrimidin-2-ylsulfanylmethyl)quinoline ligand, and one N atom of CH 3 CN, in a distorted trigonal pyramidal geometry. The cis bond angles around the Ag I atom range from 90.8 (2) to 143.48 (11) .

📜 SIMILAR VOLUMES

Bis[8-(4-pyridylsulfanylmethyl-κN)quinol
Bis[8-(4-pyridylsulfanylmethyl-κN)quinoline]silver(I) trifluoro­methane­sulfonate
✍ Song, Rui-Feng ;Wang, Yu-Hong 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB

The title mononuclear complex, [Ag(C 15 H 12 N 2 S) 2 ]CF 3 SO 3 , reveals the molecular symmetry C 2 with the Ag atom located on a crystallographic twofold axis. The Ag I centre is coordinated by two pyridine N-donors of two 8-(4pyridylsulfanylmethyl)quinoline ligands in an almost linear geometry.

catena-Poly­[[silver(I)-μ-1,2-bis(4-pyri
catena-Poly­[[silver(I)-μ-1,2-bis(4-pyridyl)­ethane-κ2N:N′] tri­fluoro­methane­sulfonate]
✍ Li, Xiaoju ;Cao, Rong ;Sun, Daofeng ;Bi, Wenhua ;Wang, Yanqin ;Hong, Maochun 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 204 KB

The title compound, {[Ag(bpe)](OTf)} n (OTf = tri¯uoromethanesulfonate) or {[Ag(C 12 H 12 N 2 )](CF 3 O 3 S)} n , has been prepared from the reaction of 1,2-bis(4-pyridyl)ethane (bpe) and Ag(CF 3 SO 3 ) in MeCN/H 2 O. The Ag I atom is twocoordinate in a slightly distorted linear arrangement, and the