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Sodium borohydride reduction of oxymercury compounds

✍ Scribed by Gray, Gerald A.; Jackson, William Roy


Book ID
126057102
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
408 KB
Volume
91
Category
Article
ISSN
0002-7863

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Photo-enhanced reduction of carbonyl com
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The reduction of ketones and some esters by sodium borohydride is dramatically accelerated by uv irradiation. The reaction seems to proceed from the (n, .rr\*) excited state of the carbonyl compound. The photocatalytic effect is dependent on the solvent polarity and substituents on aromatic carboxyl