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Reduction of organic halogen compounds by sodium borohydride

✍ Scribed by Bell, Harold Morton; Vanderslice, C. Warren; Spehar, Andrea

Book ID
121404560
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
566 KB
Volume
34
Category
Article
ISSN
0022-3263

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Photo-enhanced reduction of carbonyl com
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✍ Jung Hoon Choi; Dae Whang Kim; Sang Chul Shim πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 243 KB

The reduction of ketones and some esters by sodium borohydride is dramatically accelerated by uv irradiation. The reaction seems to proceed from the (n, .rr\*) excited state of the carbonyl compound. The photocatalytic effect is dependent on the solvent polarity and substituents on aromatic carboxyl