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Reduction of Nitroaromatic Compounds with Sodium Borohydride

✍ Scribed by Kaplan, Lloyd A.


Book ID
118146115
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
262 KB
Volume
86
Category
Article
ISSN
0002-7863

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The reduction of ketones and some esters by sodium borohydride is dramatically accelerated by uv irradiation. The reaction seems to proceed from the (n, .rr\*) excited state of the carbonyl compound. The photocatalytic effect is dependent on the solvent polarity and substituents on aromatic carboxyl