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Sodium Borohydride – Ammonium Carbonate: An Effective Reducing System for Aldehydes and Ketones

✍ Scribed by Farajollah Mohanazadeh; Mostafa Hosini; Mahmoud Tajbakhsh

Publisher
Springer Vienna
Year
2005
Tongue
English
Weight
50 KB
Volume
136
Category
Article
ISSN
0026-9247

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Ab.m.ac~: The combination of sodium borohydride and amberlyst-1501+) in tetrahydrofurane is a powerful reductor for unreactive ketones. The reduction is fast, high-yielding and the work-up is extremely simple. Ketals, silyl ethers and other organic functions are not disturbed during the reduction.

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Sodium Borohydride-Amberlyst-15(H+): An Effective Reductor for Hindered and Unreactive Ketones in Aprotic Solvent. -The first application of an exchanged-acid resin to the reduction of ketones by sodium borohydride in an aprotic solvent is presented. A variety of organic functions like ketals and s