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Sodium borohydride-amberlyst-15 (H+): An effective reductor for hindered and unreactive ketones in aprotic solvent

✍ Scribed by Juana Robles Caycho; Fernando García Tellado; Pedro de Armas; José Juan; Marrero Tellado


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
154 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


Ab.m.ac~: The combination of sodium borohydride and amberlyst-1501+) in tetrahydrofurane is a powerful reductor for unreactive ketones. The reduction is fast, high-yielding and the work-up is extremely simple. Ketals, silyl ethers and other organic functions are not disturbed during the reduction.


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ChemInform Abstract: Sodium Borohydride-
✍ J. ROBLES CAYCHO; F. GARCIA TELLADO; P. DE ARMAS; J. J. MARRERO TELLADO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Sodium Borohydride-Amberlyst-15(H+): An Effective Reductor for Hindered and Unreactive Ketones in Aprotic Solvent. -The first application of an exchanged-acid resin to the reduction of ketones by sodium borohydride in an aprotic solvent is presented. A variety of organic functions like ketals and s