<p>Although size exclusion chromatography (SEC) is perhaps the most popular and widely used technique for determining the molecular weight distribution of polymeric materials, there have been very few texts written on this topic. During the past decade, SEC has experienced a considerable amount of g
Size Exclusion Chromatography
β Scribed by B. J. Hunt (auth.), Dr B. J. Hunt, Dr S. R. Holding (eds.)
- Publisher
- Springer US
- Year
- 1989
- Tongue
- English
- Leaves
- 292
- Edition
- 1
- Category
- Library
No coin nor oath required. For personal study only.
β¦ Synopsis
There is a large and increasing variety of polymers currently in use both for domestic and industrial applications. The properties of polymers are deterΒ mined not only by their chemical type, but also by their molecular mass and molecular mass distributions. However, while the chemical type of polymers can be determined relatively easily, the average molecular masses and molecular mass distributions are more difficult to measure. The molecular mass averages of a polymer are measured by specialized and complex techniques such as light scattering (for weight average) and osmometry (for number average). Thus, complete characterization of the molecular mass distribution of a polymer by such means requires separating the sample into many fractions which can then be examined individually. Since size exclusion chromatography was introduced as a rapid and straightforward technique for the characterization of polymer molecular mass distributions, there have been tremendous increases in development and applications, and it was felt appropriate to bring together into a single volume the information required by scientists from many disciplines who wish to use the technique. This book should be useful to existing users, those who are new to the technique, and those who may be familiar with the basic technique and now wish to extend their capabilities to more complex applications (or to consider the potential of a number of related techniques). The book will also be of general interest to the experienced liquid chromatographer.
β¦ Table of Contents
Front Matter....Pages i-x
Front Matter....Pages 1-1
Theoretical background....Pages 3-13
Instrumentation and practice....Pages 14-41
Calibration and data analysis....Pages 42-53
Front Matter....Pages 55-55
High-temperature size exclusion chromatography....Pages 57-99
Copolymer analysis....Pages 100-132
Size exclusion chromatography of small molecules....Pages 133-169
Aqueous size exclusion chromatography....Pages 170-188
Front Matter....Pages 189-189
Field-flow fractionation: an alternative to size exclusion chromatography....Pages 191-216
Supercritical fluid chromatography....Pages 217-247
Hydrodynamic chromatography....Pages 248-270
Back Matter....Pages 271-286
β¦ Subjects
Chromatography; Science, general
π SIMILAR VOLUMES
<br> Content: Particle size analysis by chromatography / A.J. McHugh, D.J. Nagy, and C.A. Silebi --<br/> Size exclusion chromatography of model latices : a feasibility study / J.E. Johnston, C.L. Cowherd, and T.B. MacRury --<br/> Particle size analysis using size exclusion chromatography / A. Husain
The rapid development of new packings for aqueous size-exclusion chromatography has revolutionized this field. High resolution non-adsorptive columns now make possible the efficient separation of proteins and the rapid and precise determination of the molecular weight distribution of synthetic polym
<br> Content: Molecular weights of copolymers obtained by gel permeation chromatography-light scattering / Wolfgang Radke and Axel H.E. MuΜller --<br/> Coupled multiangle light-scattering and viscosimetric detectors for size exclusion chromatography with application to polyelectrolyte characterizati
This outstanding single-source reference details the practical use of size exclusion chromatography (SEC) in characterizing the molecular weight distribution of important polymeric materials;addressing problems encountered in the SEC of specific substances, including copolymers, polyamides, polyviny
This outstanding single-source reference details the practical use of size exclusion chromatography (SEC) in characterizing the molecular weight distribution of important polymeric materials;addressing problems encountered in the SEC of specific substances, including copolymers, polyamides, polyviny