Site-selective spectroscopy and level ordering in C-phycocyanine
✍ Scribed by W. Köhler; J. Friedrich; R. Fischer; H. Scheer
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 438 KB
- Volume
- 143
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
We present a combined fluorescence and hole-burning study of the biliprotein C-phycocyanin. Sharp zero-phonon holes compare with a broad structureless fluorescence. This finding is rationalized in terms of the special level structure in this pigment, the fast energy-transfer processes and a lack of correlation of the energies of the emissive states.
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A theoretical model is presented which describes quantitative!y the elimination of the inhomogeneous broadening in luminescence spectra of impurity centres on site-selective laser escitation. The model esplains our expcrimenial data showing a remarkable dependence of the cxitation selectivity on the