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Singlet oxygen mediated fragmentation of amino alcohols, 1,2-diamines, and amino ketones

✍ Scribed by Haugen, Christian M.; Bergmark, William R.; Whitten, David G.

Book ID
111864909
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
654 KB
Volume
114
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

Oxidative carboncarbon bond cleavage re
Oxidative carboncarbon bond cleavage reaction of 1,2-diamines and 1,2-amino alcohols under an oxygen atmosphere
✍ Makoto Shimizu; Hiroaki Makino 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 63 KB

Under an atmosphere of oxygen 1,2-diamines underwent clean oxidative cleavage in the presence of BF 3 •OEt 2 to give imines in good to excellent yields. 1,2-Amino alcohols were also cleaved under the same conditions to give imines and aldehydes in good yields.