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Oxidative carboncarbon bond cleavage reaction of 1,2-diamines and 1,2-amino alcohols under an oxygen atmosphere

✍ Scribed by Makoto Shimizu; Hiroaki Makino

Book ID: 104231990
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 63 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01945-1

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✦ Synopsis

Under an atmosphere of oxygen 1,2-diamines underwent clean oxidative cleavage in the presence of BF 3 •OEt 2 to give imines in good to excellent yields. 1,2-Amino alcohols were also cleaved under the same conditions to give imines and aldehydes in good yields.

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