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Single-Electron Oxidation of Tungsten Acetylide Complexes [(η5-C5H5)(CO)(NO)W–C≡C–R]Li

✍ Scribed by Junes Ipaktschi; Frank Munz


Book ID
102170646
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
124 KB
Volume
2006
Category
Article
ISSN
1434-1948

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Reactivity of the Inversely Polarised Ar
✍ Lothar Weber; Philipp Bayer; Gabriel Noveski; Hans-Georg Stammler; Beate Neumann 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)–As=C(NMe~2~)~2~ (11) afforded the novel η^2^‐1‐arsaallene complexes [η^2^‐{__t__BuC(O)–As=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi