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Solution and low temperature matrix photolyses of the isosteric complexes MN(η5-C5H5)(CO)3, Cr(η5-C5H5)(CO)2NO and V(η5-C5H5)(CO)(NO)2

✍ Scribed by M. Herberhold; A.J. Rest

Publisher
Elsevier Science
Year
1981
Weight
63 KB
Volume
17
Category
Article
ISSN
0047-2670

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Ab initio CI calculations on the ionized
Ab initio CI calculations on the ionized states of [Co2(η5-C5H5)2(CO)2] and [Co2(η5-C5H5)2(NO)2]
✍ Geoffrey E. Quelch; Ian H. Hillier 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 394 KB

The ionized states of [CO~(~~-C~H,)~(CO)~] and [Co,($-C,H,),(NO),] are investigated by a CI method which allows for electron reorganization, positive hole localization, and includes part of the correlation energy. Qualitative bonding schemes and the photoelectron spectra are discussed in terms of th