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η 2 -Alkynyl and Vinylidene Transition Metal Complexes. 8. 1 Synthesis of Bimetallic Tungsten Gold Complexes by Addition of ClAuPPh 3 to the Acetylide Li[(η 5 -C 5 H 5 )(CO)(NO)W(C⋮C−R)]

✍ Scribed by Ipaktschi, Junes; Munz, Frank


Book ID
127260180
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
74 KB
Volume
21
Category
Article
ISSN
0276-7333

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Synthesis and Structure of the First η3-
✍ Lothar Weber; Gabriel Noveski; Ulrich Lassahn; Hans-Georg Stammler; Beate Neuman 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 1 views

## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C