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Homogeneous catalysis by transition metal complexes. Part VI: Hydroformylation of 1-octene catalysed by [η5-C5R5M(CO)2X] and [η5-C5R5M(CO)2]2 species (R = H, CH3, C6H5; M = Fe, Ru; X = Cl, Br, I)

✍ Scribed by A. Fusi; E. Cesarotti; R. Ugo

Publisher
Elsevier Science
Year
1981
Weight
586 KB
Volume
10
Category
Article
ISSN
0304-5102

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Heterometallic analogues of [{M(CO)2(η-C
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Synthesis and Structure of the First η3-1,2-Diphosphaallyl Complexes [(η5-C5H5)(CO)2M{η3-RPPC(SiMe3)2}] (M = Mo, R = tBu, Cy; M = W, R = tBu) from [(η5-C5H5)(CO)2M=P=C(SiMe3)2] (M = Mo, W) and Inversely Polarized Phosphaalkenes RP=C(NMe2)2 (R = tBu, Cy)
✍ Lothar Weber; Gabriel Noveski; Ulrich Lassahn; Hans-Georg Stammler; Beate Neuman 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 1 views

## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C