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Single and unsupported RuHRu bond: Preparation and crystal structure of {Ru2H(μ-H)Cl(syn-Me4[14]aneS4)2}Cl (Me4[14]aneS4 = 1,4,8,11-tetrathiacyclotetradecane)

✍ Scribed by Toshikatsu Yoshida; Tomohiro Adachi; Toshihiro Tanaka; Fumitaka Goto


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
333 KB
Volume
428
Category
Article
ISSN
0022-328X

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W e were interested i n examining s i n g l e c r y s t a l s containing the triruthenium anion I R u ~( ~Y C = ~N ~~) (p-a))3(CO),l-which we obtain q u a n t i t a t i v e l y as t h e quanidinim salt, l a , i n the treatment of R U ~( C O ) ~~ with CfNMe2)4.'1/ When c r y s t a l s of l a proved u