Intramolecular vibration-vibration energy transfer cross sections have beer. calculated for COz (0001) + H2,!Dz -+ COz(ll'0) + Hz/Dz,+ C02(10Β°0) + Hz/D\*, and-C02(20Β°0) + Hz/D2 based on the mechanism that the energy mismatch is transferred to the translational motion. For CO2 + Hz. the calculated cr
Simultaneous vibration-vibration and vibration-translation transitions in H2 + D2 at high collision energies
β Scribed by H.K. Shin; P.L. Altick
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 330 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The couplmg between W and VT t~ans~hons in HZ(~) + Dz(O) -Hz(l) + D2(1) and D2(2) + Hz(O) -D2(l) f Hz(L) at hl_gh colhnon energies is investigated by use of the solution of the Schrodmger equation of motion
The coupling is sufficiently important that the energy exchange processes cannot be described by the W mecharusm alone
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Vibrational relaxation in Dz-Kr and D a-Kr-He mivtures has been measured behind incident shock waves in the temperatUre range 1400-3500"K, and VahIes 0fPrD2\_\_He, the vibrational relaxation time of Dt infinitely dilute in one atmosphere pressure of He, are derived. These values are compared with ca
Resonant vibrational excitation by e-impact has been investigated in N02. Differential cross sections for elastic and vibrational excitation present complex structures which are not simple, due 10 overlapping bands. Nevertheless, they indicate a longlived resonance ('A, ) below 1 eV and an intermedi