State-to-state branching ratios are reported for vibrational energy transfer in benzene and benzene-d6 due to collisions with Dz and with He in a supersonic free jet expansion. In both the benzene and benzene-d6 experiments the initial vibrational level pumped was 6'. The state-to-state branching ra
Vibrational energy transfer in D2-He collisions
β Scribed by P.F. Bird; W.D. Breshears
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 341 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Vibrational relaxation in Dz-Kr and D a-Kr-He mivtures has been measured behind incident shock waves in the temperatUre range 1400-3500"K, and VahIes 0fPrD2__He, the vibrational relaxation time of Dt infinitely dilute in one atmosphere pressure of He, are derived. These values are compared with calculations closely approximating exact one-dimensional quantum mechanical resu!is. which were obtained using Hz-He potential parameters from recent theoretical and experimental determinations.
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Intramolecular vibration-vibration energy transfer cross sections have beer. calculated for COz (0001) + H2,!Dz -+ COz(ll'0) + Hz/Dz,+ C02(10Β°0) + Hz/D\*, and-C02(20Β°0) + Hz/D2 based on the mechanism that the energy mismatch is transferred to the translational motion. For CO2 + Hz. the calculated cr
We study vrbrarional energy transfer in rnelastic collmear collisions betBeen IWO diaromrc molecules The system is represemed by IWO linearly driven parametric oscillators with a bilinear\_ time-dependent residua1 coupling between them. We amu& for Ihe time evolution of the Irncarly dnvcn par;lmetri
Vibration-t~v~ration energy transfer rates for collision between two CO molecules arc calculated. Rcsul~ obtained are compared with recent experiments and theoretical valtys. it is pointed out that none of the existing wIcuIatians gives a complete clccount of the available experimental data.