Simultaneous Primary and Secondary Coordination of a Neutral Guest within a Macrocyclic Complex of Rhodium(III)
β Scribed by Prof. George Ferguson; Karen E. Matthes; Dr. David Parker
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 214 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Metal ion complexes of polyaza macrocyclic ligands have been the subject of extensive investigations over the past decade [2-S] ; however, there are very few reports of scandium(II1) complexes containing these ligands in spite of the demonstrated ability of the scandium(II1) ion to form strong
The binuclear cyclometallated complex [RhCl -Cl bBzlH 2 bz ] 2 [bBzlH 2 bzH D 1,3-bis(benzimidazolyl)benzene] undergoes a dichloro bridge cleavage reaction with 2,2 0 -bipyridine (bipy) or 1,10-phenanthroline (phen) in the presence of perchlorate to yield a mononuclear complex of the type RhCl OClO