Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(III) and Iridium(III) Bearing a Pentamethylcyclopentadienyl Group

Circularly polarized luminescence and st

Circularly polarized luminescence and structural studies of a dysprosium(III) complex with an octadentate macrocyclic ligand bearing benzylphosphinate groups

✍ Rudy L Luck; Christina L Maupin; David Parker; James P Riehl; J.A Gareth William 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 221 KB

The solution and solid-state structures of a Dy(III) complex with 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetryltetramethylenetetra(benzylphosphinate) have been examined by means of circularly polarized luminescence spectroscopy and crystallographic methods. The spectroscopic measurements show that