✦ LIBER ✦

Simple route to chiral organophosphorus compounds

✍ Scribed by Oleg I. Kolodiazhnyi; Evgen V. Grishkun

Book ID: 103977449
Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 176 KB
Volume: 7
Category: Article
ISSN: 0957-4166
DOI: 10.1016/0957-4166(96)00093-6

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✦ Synopsis

Reaction of chlorides of nonsymmetrically substituted phosphinic and phosphinous acid with (-)-l,2:3,5-disubstituted-ct-D-glucofuranose proceeds with very high stereoselectivity to give stereochemically pure phosphinic and phosphinous acid esters, which are starting reagents for preparation of chiral organophosphorus compounds. Stereoselectivity of the reaction depends on the nature of bases, solvent, temperature and excess of chlorophosphine.

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