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ChemInform Abstract: nBuLi-Mediated Hydrophosphination: A Simple Route to Valuable Organophosphorus Compounds.

✍ Scribed by Arnaud Perrier; Virginie Comte; Claude Moise; Philippe Richard; Pierre Le Gendre


Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
41
Category
Article
ISSN
0931-7597

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nBuLi-Mediated Hydrophosphination: A Sim
✍ Arnaud Perrier; Virginie Comte; Claude MoΓ―se; Philippe Richard; Pierre Le Gendre πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 493 KB

## Abstract A straightforward synthesis of homoallyl‐ and allylphosphanes has been developed using __n__BuLi‐mediated hydrophosphination of conjugated dienes. In all the cases the phosphorus atom of the reacting phosphane attacked thesterically less demanding side of the diene exclusively. In addit

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